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XFEL Studies Confirm Mixed Crystal Structures in Superionic Water

The finding refines models of ice-giant interiors by showing oxygen lattices can share close-packed sequences.

Overview

  • Peer-reviewed experiments observed coexisting atomic packings in superionic water, including BCC with FCC as well as FCC with HCP stacking under the same conditions.
  • The team created extreme states with laser-driven shocks and captured trillionth-of-a-second X-ray diffraction, resolving subtle lattice signatures at pressures above 1.5 million atmospheres and thousands of degrees Celsius.
  • Results from SLAC's LCLS (MEC) were independently reproduced at the European XFEL (HED-HIBEF), strengthening confidence in the mixed close-packed interpretation.
  • Because freely moving hydrogen ions conduct electricity through a rigid oxygen lattice, the structural diversity informs explanations for the unusual magnetic fields of Uranus and Neptune.
  • The work, published in Nature Communications on December 7, 2025, will be integrated into simulations, with planned measurements targeting electrical conductivity and compositional effects.