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Voltage Protocols Unlock Viable Path for Large-Format LMR Cells

Operation changes that restore oxidized oxygen reduce gas build-up, thereby opening a practicable path to commercial-scale LMR cells.

Overview

  • LG Energy Solution and Seoul National University published a peer-reviewed Nature Communications paper on Monday, September 7, 2026, reporting operational protocols that cut gas generation and improved large-format LMR cell stability.
  • Lowering the upper charge cutoff from 4.6 V to 4.3 V raised the fraction of oxidized oxygen that is reduced on discharge from about 86% to about 97%, which limits irreversible oxygen loss.
  • Reducing the discharge cutoff to 2.0 V and using a lower-temperature formation process helped restore oxidized oxygen nearly fully and suppressed gas build-up inside 40 Ah cells.
  • Applied to 40 Ah-class large-format cells, the optimized protocol produced 92.2% energy retention after 883 charge-discharge cycles, showing cycle life that addresses a key barrier to EV use.
  • Wider commercialization still requires safety testing, OEM qualification and manufacturing adaptation, but successful scale-up could cut cobalt use by substituting manganese and lower battery material costs.