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Vitamin B2–Glucose Flow Battery Shows Promising Power, Reveals Stability Hurdles

The prototype swaps noble metals for a vitamin mediator, with researchers now targeting light-driven degradation.

Overview

  • PNNL researchers built a riboflavin-mediated glucose flow cell using carbon electrodes and either potassium ferricyanide or oxygen as the catholyte.
  • In the ferricyanide configuration, the cell delivered room‑temperature power density comparable to vanadium flow batteries.
  • The glucose–oxygen design achieved a peak power density of about 13 milliwatts per square centimeter, roughly 20 times higher than previous glucose flow reports under similar conditions.
  • Oxygen in the presence of light degraded riboflavin, leading to self‑discharge and slower electrode reactions that the team aims to fix through engineering and light management.
  • The peer‑reviewed work in ACS Energy Letters acknowledges DOE‑linked funding, with authors presenting it as a proof‑of‑concept toward safer, low‑cost storage using non‑toxic components.