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Trace Metal Ions Enable Reversible Control of Potassium Transport in Biomimetic Nanochannels

Simulations reveal ion-induced dipole mechanisms paving the way for membranes capable of purifying water or extracting lithium.

Scientists have developed a tunable system that selectively controls chemical transport at the atomic scale, mimicking cells’ abilities to mind their own biological membranes.
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Overview

  • Researchers engineered angstrom-scale 2D nanochannels that mimic cellular ion gates to selectively regulate potassium flow.
  • A 1 percent increase in lead ions bound to acetate groups doubled potassium transport by forming neutral potassium-chloride pairs.
  • Cobalt and barium ions compete for binding sites and inhibit potassium passage by disrupting neutral ion pair formation.
  • Custom non-equilibrium molecular dynamics simulations incorporating ion-induced dipole interactions confirmed the experimental transport behaviors.
  • The team is now adapting the tunable system to other materials and ions, with a focus on lithium recovery and advanced water-purification applications.