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Sealed Apollo 17 Sample Reveals Exotic Sulfur Signature Unlike Earth’s

The peer‑reviewed analysis points to early lunar photochemistry or a Theia inheritance as competing explanations.

Overview

  • Brown University researchers report the finding in JGR: Planets after using secondary ion mass spectrometry to measure sulfur isotopes.
  • The analyzed material came from an Apollo 17 double drive tube collected at Taurus-Littrow and preserved in a helium chamber under NASA’s ANGSA program.
  • Volcanic sulfur in the sample is highly depleted in sulfur‑33, diverging strongly from isotope ratios seen in terrestrial sulfur.
  • The team outlines a scenario involving UV-driven reactions in a short‑lived, optically thin early lunar atmosphere, which would imply ancient surface‑to‑mantle exchange on the Moon.
  • An origin tied to material from Theia remains plausible, and the authors call for broader isotope comparisons, including Mars samples, to distinguish between the hypotheses.