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Pilot Reactor Uses Recycled Solar Silicon to Convert Power Plant CO₂

Researchers demonstrated that acid-treated silicon wafers from discarded solar panels can convert untreated exhaust CO₂ into valuable chemicals at pilot scale.

Old obsolete solar panels in factory yard.
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Overview

  • The study by Yokohama National University and partners was published on July 14 in ACS Sustainable Resource Management
  • Acid pretreatment with hydrochloric acid removes aluminum contaminants and enhances the silicon powder’s electron-donating reactivity toward CO₂
  • A direct connection between the reactor and a thermal power plant exhaust stream allowed conversion of 14% CO₂ without any gas purification
  • The process achieved formic acid yields of up to 73% and also produced nitrogen-containing formamides when amines were introduced
  • By valorizing both end-of-life photovoltaic panels and greenhouse gas emissions, the method exemplifies a circular-economy approach to chemical production