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MoS₂ Thin Films Boost Anode-Free Solid-State Battery Lifespan Sevenfold

A sacrificial MoS₂ coating suppresses lithium dendrites to bolster stability, with practical deployment targeted for 2032.

Stainless steel (SUS) cut into square pieces and placed in a metal-organic chemical vapor deposition (MOCVD) system for coating with molybdenum disulfide (MoS₂) thin films.
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Overview

  • Researchers used metal-organic chemical vapor deposition to apply MoS₂ nanosheet thin films onto stainless steel current collectors as a scalable and affordable interface coating.
  • Cells with MoS₂-coated current collectors operated stably for over 300 hours, compared with about 95 hours for cells using bare stainless steel.
  • Full-cell prototypes showed initial discharge capacity rising from 136.1 to 161.1 mAh/g and capacity retention improving from 8.3% to 58.9% after 20 cycles.
  • During cycling, MoS₂ converts to molybdenum metal and lithium sulfide to form a lithiophilic interlayer that suppresses dendrite growth and strengthens interfacial stability.
  • The team anticipates practical deployment by 2032 with funding from the Korea Research Institute of Chemical Technology and the National Research Foundation of Korea.