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Iron Carbonate, Not Phosphate, Preserved Biomolecules in Ancient Coprolites

A Curtin-led study identifies a repeatable mineral–molecule pattern that can guide targeted searches for dietary biomarkers.

Overview

  • A peer-reviewed Geobiology paper published September 19, 2025 reports that microscopic iron carbonate grains shielded delicate biomolecules in coprolites roughly 300 million years old.
  • The team analyzed specimens mostly from the Mazon Creek site in Illinois, where the coprolites were already known to contain cholesterol derivatives indicating a meat-based diet.
  • Phosphate minerals were linked to preserving fossil structure but were not the agents protecting molecular traces in the studied samples.
  • Researchers extended the work to diverse fossils across species, environments, and time periods and observed the same carbonate–biomolecule association.
  • The authors say mineralogical criteria can now steer fieldwork and laboratory analyses to recover molecular evidence of ancient diets and ecosystems more efficiently.