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Electron Beam Irradiation Breaks Down PTFE at 370 °C Using 50% Less Energy

This technique produces reusable fluorocarbons that could enable industrial-scale recycling of PTFE waste

Researchers have put forth a promising method for enhancing the energy efficiency of PTFE recycling. (Representational image)
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Overview

  • QST researchers achieved full PTFE decomposition at 370 °C with a 5 MGy electron beam, compared to only 10% breakdown at 30 °C and 86% at 270 °C.
  • The combined electron beam irradiation and moderate heating slashes energy requirements by 50%, cutting typical pyrolysis consumption from about 2.8–4 MWh per ton to roughly 1.4–2 MWh per ton.
  • Decomposition yields oxidized fluorocarbons and perfluoroalkanes that can be captured and reused as feedstocks in chemical manufacturing.
  • High-temperature irradiation enlarges PTFE’s internal crystal units, accelerating breakdown and boosting energy efficiency.
  • Researchers project that the method’s energy savings could make industrial-scale recycling of fluoropolymers commercially viable for PTFE waste generators.