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Earliest Direct Evidence Shows Hunters Used Poisoned Arrows 60,000 Years Ago

Alkaloids on quartz tips match the poison bulb, indicating deliberate use of plant toxins.

Overview

  • Researchers tested 10 quartz points from the Umhlatuzana Rock Shelter in KwaZulu-Natal, finding toxic residues on five.
  • Targeted microchemical and biomolecular analyses identified Amaryllidaceae alkaloids, including buphandrine and epibuphanisine.
  • Chemical signatures point to Boophone disticha as the most likely source, consistent with toxins on later historical arrowheads.
  • The poison would have slowed prey rather than killing instantly, suggesting planning and cause‑and‑effect reasoning in hunting.
  • Published in Science Advances, the study moves the earliest confirmed use of poisoned hunting weapons far earlier than mid‑Holocene examples.