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Earliest Direct Evidence of Poisoned Arrows Found on 60,000-Year-Old Tips in South Africa

Chemical signatures of a toxic bulb reveal sophisticated planning and tracking by early hunters.

Overview

  • A Science Advances paper published January 7 reports plant-alkaloid residues on five microlithic arrow tips from the Umhlatuzana Rock Shelter in KwaZulu-Natal.
  • Analyses identified buphandrine and epibuphanisine, compounds linked to Boophone disticha (gifbol), on the quartz points.
  • Geochemical and magnetic tests corroborated the ~60,000-year context, and gas chromatography–mass spectrometry detected the stable toxins.
  • Residues closely matched those on 18th-century southern African arrows in Swedish museum collections, suggesting long-standing knowledge or repeated rediscovery.
  • The evidence pushes confirmed use of weaponized toxins far earlier than the previous <7,000-year record, and the slow-acting poison implies hunters tracked wounded prey for prolonged periods, with researchers noting other labile toxins may no longer be detectable.