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Earliest Confirmed Use of Blue Pigment in Europe Found on Paleolithic Paint Palette in Germany

Advanced testing identified azurite on a 13,000–14,000-year-old palette, prompting a reevaluation of blue’s largely invisible role in Paleolithic life.

Overview

  • The findings, published in Antiquity on September 29, are based on 2023–2024 laboratory analyses of a long-held museum artifact from Mühlheim-Dietesheim.
  • Proton Induced X-ray Emission and related techniques confirmed the residue as ground azurite, a copper-based blue mineral.
  • A bowl-shaped stone previously catalogued as an oil lamp is now interpreted as a small paint-mixing palette.
  • Researchers propose the blue was likely used on skin, textiles, or objects that seldom preserve, explaining its rarity in surviving cave art.
  • Recovered at a Magdalenian riverside campsite near the River Main east of Frankfurt, the discovery is presented as a starting point for broader pigment searches using modern detection methods.