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Basel Molecule Stores Four Light-Made Charges in Stepwise Advance Toward Artificial Photosynthesis

A two-flash method operates under much dimmer light to guide next steps toward coupling the stored charges to fuel-making catalysts.

As with natural photosynthesis, the new molecule temporarily stores two positive and two negative charges.
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Sunlight for fuel | Image: Unsplash

Overview

  • The University of Basel team designed a five-part donor–photosensitizer–acceptor molecule that accumulates two positive and two negative charges after two light pulses.
  • The stepwise excitation reduces the need for the extremely intense laser light used in earlier studies and moves closer to sunlight-like conditions.
  • The separated charges persist long enough to be usable for subsequent chemistry, addressing a core hurdle for multi-electron reactions such as water splitting.
  • Researchers led by Professor Oliver Wenger, with lead author Mathis Brändlin, detailed the proof-of-concept in Nature Chemistry.
  • The work is not yet a complete artificial photosynthesis system, with upcoming efforts focused on linking the charge-storage module to catalytic fuel-forming reactions.